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MSDS No. EW326151 Issue Date: 2004/06/16 |
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| CODE: | 322-61512, 324-61511 |
| PRODUCT NAME : | Ammonium Pentadecafluorooctanoate |
| MANUFACTURER : | Wako Chemical K.K. |
| SUPPLIER : | SUPPLIER(In JAPAN) : Wako Pure Chemical Industries, Ltd. ADDRESS : 1-2, Doshomachi 3-chome, Chuo-ku, Osaka, 540-8605, Japan TELEPHONE NUMBER & EMERGENCY TELEPHONE NUMBER: (06)6203-3741 SUPPLIER(In U.S.A.) : Wako Chemicals USA, Inc. ADDRESS : 1600 Bellwood Road, Richmond, VA 23237, U.S.A. TELEPHONE NUMBER : (804)271-7677 EMERGENCY TELEPHONE NUMBER : (800)424-9300 (CHEMTREC) SUPPLIER(In EUROPE) : Wako Chemicals GmbH, Germany ADDRESS : Nissanstrasse 2,D-41468 Neuss, GERMANY TELEPHONE NUMBER & EMERGENCY TELEPHONE NUMBER : (02131)311-0 |
| CHEMICAL NAME : | Ammonium Pentadecafluorooctanoate |
| SYNONYMS : | Octanoic acid, pentadecafluoro-, ammonium salt; DS101; Fluorad FC 143 Unidyne DS 101 |
| FORMULA : | C8H4F15NO2 |
| MOLECULAR WEIGHT : | 431.10 |
| CAS NUMBER : | 3825-26-1 |
| TSCA INVETORY : | Listed |
| EINECS No. : | 223-320-4 |
| IDENTIFICATION OF DANGER ; | |
| SYMBOL : | Xn |
| R-phrases : | 20/22-36/38 |
| Harmful by inhalation and if swallowed. Irritating to eyes and skin. |
| GENERAL ADVICE : | Wash off immediately with soap and plenty of water. In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust impervious protective suit. Use personal protective equipment. |
| INHALATION : | Move victim to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, administer artificial respiration. Maintain normal body temperature with a blanket. If irritation persists, transport to a hospital immediately. |
| SKIN CONTACT : | Remove contaminated clothes and shoes, rinse skin with plenty of water or shower. Use soap to help assure removal. If irritation persists, transport to a hospital immediately. |
| EYE CONTACT : | Remove any contact lenses at once. Flush eyes well with flooding amounts of running water for at least 15 minutes. Assure adequate flushing by separating the eyelids with sterile fingers. If irritation persists, transport to a hospital immediately. |
| INGESTION : | Rinse mouth, give plenty of water to dilute the substance. Never give anything by mouth to an unconscious person. Transport to a hospital immediately. |
| EXTINGUISHING MEDIA : | Carbon dioxide, dry chemical powder, foam, water |
| FIRE & EXPLOSION HAZARDS : | Toxic, irritating dust or smoke may be emitted. |
| SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS : | Firemen should wear normal protective equipment(full bunker gear)and positive-pressure self-contained breathing apparatus. |
| PERSONAL PRECAUTIONS : | Remove ignition sources and ventilate the area. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid raising dust and avoid contact with skin and eyes. |
| ENVIRONMENTAL PRECAUTIONS : | Prevent spills from entering sewers, watercourses or low areas. |
| METHODS FOR CLEAN UP : | Do not touch spilled material without suitable protection(See section 8). After material is completely picked up, wash the spill site with soap and water and ventilate the area. Put all wastes in a plastic bag for disposal and seal it tightly. Remove, clean, or dispose of contaminated clothing. |
| Research use only. | |
| HANDLING : | Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Handle material with suitable protection. |
| STORAGE : | Store away from sunlight in well-ventilated dry place at room temperature. Keep container tightly closed. |
| INCOMPATIBLE PRODUCTS : | Oxidizers, alkalies and reducing agents |
| ENGINEERING MEASURES : | Use exhaust ventilation to keep airborne concentrations below exposure limits. Use only with adequate ventilation. |
| VENTILATION : | Local Exhaust ; Necessary, Mechanical(General) ; Necessary Special; Closed system is recommended. |
| CONTROL PARAMETER : |
| OSHA Final Limits : | None established |
| ACGIH TLV(s) : | TWA= 0.01mg/m3; skin notation |
| PERSONAL PROTECTION ; | |
| Respiratory protection : | NIOSH/MSHA approved respirator |
| Hand protection : | Chemical resistant gloves |
| Eye protection : | Safety glasses(goggles) |
| Skin protection : | Protective clothing |
| APPEARANCE : | White-pale yellow, crystals or crystalline powder |
| ODOR : | Characteristic odor |
| pH : | Not available |
| BOILING POINT : | Not available |
| MELTING POINT : | 160-167 °C= 320.0-332.6 °F |
| FLASH POINT : | Not available |
| FLAMMABILITY (solid, gas) : | Not available |
| DECOMPOSITION TEMPERATURE : | Not available |
| EXPLOSIVE LIMITS : | Not available |
| VAPOR PRESSURE : | Not available |
| SPECIFIC GRAVITY : | Not available |
| SOLUBILITY IN ; | |
| WATER : | Freely soluble (> 10wt% at 20 °C= 68 °F) |
| ACETONE : | Freely soluble (> 10wt% at 20 °C= 68 °F) |
| log Po/w : | Not available |
| CONDITION TO AVOID : | Sunlight, heat |
| INCOMPATIBILITY(MATERIAL TO AVOID) : | Oxidizers, alkalies and reducing agents |
| HAZARDOUS DECOMPOSITION PRODUCTS : | Carbon monoxide, nitrogen oxides and fluorine compounds may be formed. |
| HAZARDOUS POLYMERIZATION : | Will not occur. |
| ACUTE TOXICITY DATA : | LD50(orl,rat): 430mg/kg(AIHAAP 41, 576, 1980) LC50(ihl,rat): 980mg/m3/4H(FCTOD7 24, 1325, 1986) LD50(skin,rabbit): 4300mg/kg(TXAPA9 81, 348, 1985) |
| IRRITATION DATA : | Eye; rabbit; 500mg/24H; Moderate(AIHAAP 41, 576, 1980) Skin; rabbit; 500mg; Moderate(TXAPA9 81, 348, 1985) |
| MUTATION DATA : | Not available |
| REPRODUCTIVE EFFECTS DATA : | TCLo(ihl,rat): 25mg/m3/6H(6-15 D preg); Effects on Embryo or Fetus-fetotoxicity(FAATDF 4, 429, 1984) TDLo(orl,rat): 5.5gm/kg(70 D preg); Effects on Newborn-viablity index(TOXID9 72, 76, 2003) |
| TUMORIGENIC DATA : | Not available |
| ADDITIONAL INFORMATION ; | |
| NTP : | Not listed |
| IARC : | Not listed |
| OSHA : | Not listed |
| ACGIH : | Animal Carcinogen (A3) |
| BIODEGRADABILITY : | Not available |
| BIOACCUMULATION POTENTIAL : | This material is bioaccumulatable. |
| AQUATIC TOXICITY : | Not available |
| OTHER INFORMATION : | WGK;2 |
| Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber in accordance with all applicable regulations. Any disposal practice must be in compliance with country, local, state, and federal laws and regulations ( contact country, local or state environmental agency for specific rules ). |
| IATA : | Not Restricted. |
| DOT(Department of Transportation) : | Not a Hazardous Material for DOT shipping. |
| US REGULATIONS ; | |
| Mass. Subst. List | |
| EPA : | CERCLA RQ= Not listed EPCRA TPQ= Not listed |
| OSHA : | TQ= Not listed |
| EU REGULATIONS ; | |
| SYMBOL : | Xn |
| R-phrases : | 20/22-36/38 |
| Harmful by inhalation and if swallowed. Irritating to eyes and skin. |
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| S-phrases : | 26-36/37/39-45 |
| In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately. |
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| EC index No. : | Not listed |
| No specific notes |
The above information is believed to be correct to be the best of our knowledge and information but does not purport to be all inclusive and shall be used only as a guide. This product is intended to be used by expert persons having chemical knowledge and skill, at their own discretion and risk and Wako shall not be held liable for any damageresulting from handling or from contact with the above material.